Publication:
Site-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysis

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CEJ-2019-OA.pdf(1.35 MB)
Date
2019-06-06
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Authors
Sahoo, Basudev ; Bellotti, Peter ; Juliá Hernández, Francisco ; Meng, Qing-Yuan ; Crespi, Stefano ; König, Burkhard ; Martin, Ruben
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Publisher
Wiley
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Química Inorgánica
DOI
https://doi.org/10.1002/chem.201902095
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info:eu-repo/semantics/article
Description
© 2019 The Authors. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Published version of a Published Work that appeared in final form in Chemistry - A European Journal. To access the final edited and published work see https://doi.org/ 10.1002/chem.201902095
Abstract
A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C@H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.
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Carbon dioxide , Carboxylation , Chain-walking , Nickel , Photocatalysis
Citation
Chem. Eur. J. 2019, 25, 9001-9005
URI
http://hdl.handle.net/10201/147919
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