Browsing by Subject "Chain-walking"

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    Site-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysis
    (Wiley, 2019-06-06) Sahoo, Basudev; Bellotti, Peter; Juliá Hernández, Francisco; Meng, Qing-Yuan; Crespi, Stefano; König, Burkhard; Martin, Ruben; Química Inorgánica
    A photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C@H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.