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Site-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysis

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dc.contributor.authorSahoo, Basudev
dc.contributor.authorBellotti, Peter
dc.contributor.authorJuliá Hernández, Francisco
dc.contributor.authorMeng, Qing-Yuan
dc.contributor.authorCrespi, Stefano
dc.contributor.authorKönig, Burkhard
dc.contributor.authorMartin, Ruben
dc.contributor.departmentQuímica Inorgánica
dc.date.accessioned2025-01-07T10:20:12Z
dc.date.available2025-01-07T10:20:12Z
dc.date.issued2019-06-06
dc.description© 2019 The Authors. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Published version of a Published Work that appeared in final form in Chemistry - A European Journal. To access the final edited and published work see https://doi.org/ 10.1002/chem.201902095
dc.description.abstractA photoinduced carboxylation of alkyl halides with CO2 at remote sp3 C@H sites enabled by the merger of photoredox and Ni catalysis is described. This protocol features a predictable reactivity and site selectivity that can be modulated by the ligand backbone. Preliminary studies reinforce a rationale based on a dynamic displacement of the catalyst throughout the alkyl side chain.
dc.formatapplication/pdfes
dc.format.extent5es
dc.identifier.citationChem. Eur. J. 2019, 25, 9001-9005
dc.identifier.doihttps://doi.org/10.1002/chem.201902095
dc.identifier.issnPrint: 0947-6539 0947-6539
dc.identifier.issnElectronic: 1521-3765
dc.identifier.urihttp://hdl.handle.net/10201/147919
dc.languageenges
dc.publisherWiley
dc.relationÁmbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO. Convocatoria: Proyectos I+D+i 2015. Nombre del proyecto: CARBOXILACION DE MATERIA ORGANICA CON DIOXIDO DE CARBONO CATALIZADA POR METALES DE TRANSICION Código: CTQ2015-65496-Res
dc.relation.publisherversionhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.20190
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCarbon dioxidees
dc.subjectCarboxylationes
dc.subjectChain-walkinges
dc.subjectNickeles
dc.subjectPhotocatalysises
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Químicaes
dc.titleSite-selective, remote sp3 C−H carboxylation enabled by the merger of photoredox and nickel catalysises
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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This is the peer reviewed version of the following article: Chem. Eur. J. 2019, 25, 9001-9005, which has been published in final form at https://doi.org/10.1002/chem.201902095. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
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