Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage

Azizollahi, Hamid; P. Mehta, Vaibhav; García-López, José-Antonio

Publication:
Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage

dc.contributor.author	Azizollahi, Hamid
dc.contributor.author	P. Mehta, Vaibhav
dc.contributor.author	García-López, José-Antonio
dc.contributor.department	Química Inorgánica
dc.date.accessioned	2021-01-27T12:21:27Z
dc.date.available	2021-01-27T12:21:27Z
dc.date.issued	2019-08-05
dc.description.abstract	We report two ligand-controlled cascade reactions relying on the intramolecular carbopalladation of skipped dienes. The use of a bulky monodentate phosphine ligand affords [4,5]-spirocycles via sequential double carbopalladation, however bidentate phosphines promote a remote β-C-elimination process which does not rely on the use of strained or sterically hindered substrates	es
dc.format	application/pdf	es
dc.identifier.citation	Chemical Communications, 2019, 55,10281-10284
dc.identifier.doi	10.1039/c9cc04817k
dc.identifier.issn	1364-548X
dc.identifier.uri	http://hdl.handle.net/10201/101815
dc.language	eng	es
dc.relation	Ámbito del proyecto (Europeo, nacional o regional): nacional Agencia/entidad financiadora: MICINN Convocatoria: 2015 Nombre del proyecto: Synthesis and Applications in Catalysis and Photocatalysis of New Types of Transition Metal Organometallic Complexes (CTQ2015-69568-P) Código: CTQ2015-69568-P Ámbito del proyecto: REGIONAL Agencia/entidad financiadora: FUNDACIÓN SÉNECA Convocatoria: 2015 Synthesis, Structure and Reactivity of New Types of Organometallic Complexes. Applications as Synthetic Intermediates, Catalysts and Photoactive Materials. (19890/GERM/15) Agencia/entidad financiadora: MICINN Nombre del proyecto: Ampliando la aplicabilidad de los compejos organometálicos de metales de transición en catálisis y fotoquímica Convocatoria: 2018 Código: PGC2018-100719-B-I00	es
dc.relation.isreplacedby	https://doi.org/10.1039/C9CC04817K	es
dc.relation.publisherversion	https://doi.org/10.1039/C9CC04817K	es
dc.rights	info:eu-repo/semantics/openAccess	es
dc.rights	Atribución-NoComercial-SinDerivadas 3.0 España	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/3.0/es/	*
dc.subject	Palladium	es
dc.subject	cascade reaction	es
dc.subject	carbopalladation	es
dc.subject	heterocycles	es
dc.subject.other	CDU::5 - Ciencias puras y naturales::54 - Química	es
dc.title	Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage	es
dc.type	info:eu-repo/semantics/article	es
dspace.entity.type	Publication	es