Publication: Pd-catalyzed cascade reactions involving skipped dienes: from double carbopalladation to remote C–C cleavage
Authors
Azizollahi, Hamid ; P. Mehta, Vaibhav ; García-López, José-Antonio
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DOI
10.1039/c9cc04817k
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info:eu-repo/semantics/article
Description
Abstract
We report two ligand-controlled cascade reactions relying on the intramolecular carbopalladation of skipped dienes. The use of a bulky monodentate phosphine ligand affords [4,5]-spirocycles via sequential double carbopalladation, however bidentate phosphines promote a remote β-C-elimination process which does not rely on the use of strained or sterically hindered substrates
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Citation
Chemical Communications, 2019, 55,10281-10284
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