Nickel-catalyzed chemo-, regio- and diastereoselective bond formation through proximal C-C cleavage of benzocyclobutenones

Juliá Hernández, Francisco; Ziadi, Asraa; Nishimura, Akira; Martin, Ruben

Publication:
Nickel-catalyzed chemo-, regio- and diastereoselective bond formation through proximal C-C cleavage of benzocyclobutenones

dc.contributor.author	Juliá Hernández, Francisco
dc.contributor.author	Ziadi, Asraa
dc.contributor.author	Nishimura, Akira
dc.contributor.author	Martin, Ruben
dc.contributor.department	Química Inorgánica
dc.date.accessioned	2025-01-07T10:06:48Z
dc.date.available	2025-01-07T10:06:48Z
dc.date.issued	2015-06-11
dc.description	© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Accepted version of a Published Work that appeared in final form in Angewandte Chemie International Edition. To access the final edited and published work see https://doi.org/10.1002/anie.201503461
dc.description.abstract	The first catalytic intermolecular proximal C1-C2 cleavage of Benzocyclobutenones (BCB) without prior carbonyl activation or employing noble metals has been developed. This protocol operates at room temperature and is characterized by an exquisite chemo-, regio- and diastereoselectivity profile, constituting a unique platform for preparing an array of elusive carbocyclic skeletons.
dc.format	application/pdf	es
dc.format.extent	5	es
dc.identifier.citation	Angew. Chem. Int. Ed. 2015, 54, 9537-9541
dc.identifier.doi	https://doi.org/10.1002/anie.201503461
dc.identifier.issn	Print: 1433-7851
dc.identifier.issn	Electronic: 1433-7851
dc.identifier.uri	http://hdl.handle.net/10201/147916
dc.language	eng	es
dc.publisher	Wiley, Gesellschaft Deutscher Chemiker
dc.relation	the European Research Council (ERC-277883) and MINECO (CTQ2012-34054 & Severo Ochoa Excellence Accreditation 2014-2018; SEV-2013-0319) and CELLEX Foundation for support. Johnson Matthey, Umicore and Nippon Chemical Industrial are acknowledged for a gift of metal and ligand sources.
dc.relation.ispartof	Ámbito del proyecto (Europeo, nacional o regional): Europeo Agencia/entidad financiadora: European Research Council. Convocatoria: Starting Grant 2011.Nombre del proyecto: Chasing a Fundamental Challenge in Catalysis: A Combined Cleavage of Carbon-Carbon Bonds and Carbon Dioxide for Preparing Functionalized Molecules. Código: ERC-StG-277883. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Proyectos I+D+i 2012 Nombre del proyecto: Nuevos métodos sintéticos para la funcionalización catalítica de enlaces inertes Código: CTQ2012-34054. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Severo Ochoa Excellence Accreditation Nombre del proyecto: Código: SEV-2013-0319
dc.relation.publisherversion	https://onlinelibrary.wiley.com/doi/10.1002/anie.201503461
dc.rights	info:eu-repo/semantics/openAccess	es
dc.rights	Attribution-NonCommercial-NoDerivatives 4.0 Internacional	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject	Benzocyclobutenones	es
dc.subject	C-C activation	es
dc.subject	Nickel catalysis	es
dc.subject	Strain rings	es
dc.subject.other	CDU::5 - Ciencias puras y naturales	es
dc.title	Nickel-catalyzed chemo-, regio- and diastereoselective bond formation through proximal C-C cleavage of benzocyclobutenones	es
dc.type	info:eu-repo/semantics/article	es
dspace.entity.type	Publication	es