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Walking metals for remote functionalization

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dc.contributor.authorSommer, Heiko
dc.contributor.authorJuliá Hernández, Francisco
dc.contributor.authorMartin, Ruben
dc.contributor.authorMarek, Ilan
dc.contributor.departmentQuímica Inorgánica
dc.date.accessioned2025-01-07T11:44:50Z
dc.date.available2025-01-07T11:44:50Z
dc.date.issued2018-02-08
dc.description© 2018 American Chemical Society. This manuscript version is made available under the CC-BY-NC 4.0 license http://creativecommons.org/licenses/by-nc/4.0/. This document is Published, version of a Published Work that appeared in final form in ACS Central Science. To access the final edited and published work see https://doi.org/10.1021/acscentsci.8b00005
dc.description.abstractThe distant and selective activation of unreactive C−H and C−C bonds remains one of the biggest challenges in organic chemistry. In recent years, the development of remote functionalization has received growing interest as it allows for the activation of rather challenging C−H and C−C bonds distant from the initiation point by means of a “metal-walk”. A “metal-walk” or “chain-walk” is defined by an iterative series of consecutive 1,2- or 1,3-hydride shifts of a metal complex along a single hydrocarbon chain. With this approach, simple building blocks or mixtures thereof can be transformed into complex scaffolds in a convergent and unified strategy. A variety of catalytic systems have been developed and refined over the past decade ranging from late-transition-metal complexes to more sustainable iron- and cobalt-based systems. As the possibilities of this field are slowly unfolding, this area of research will contribute considerably to provide solutions to yet unmet synthetic challenges.
dc.formatapplication/pdfes
dc.format.extent13es
dc.identifier.citationACS Cent. Sci. 2018, 4, 2, 153–165
dc.identifier.doihttps://doi.org/10.1021/acscentsci.8b00005
dc.identifier.issnElectronic: 2374-7951
dc.identifier.urihttp://hdl.handle.net/10201/147932
dc.languageenges
dc.publisherAmerican Chemical Society
dc.relationICIQ, European Research Council under the Seventh Framework Program of the European Community for the Israeli PI (ERC Grant Agreement 338912) and MINECO (CTQ2015-65496-R & Severo Ochoa Accreditation SEV-2013-0319) for financial support.
dc.relation.ispartofÁmbito del proyecto (Europeo, nacional o regional): Europeo Agencia/entidad financiadora: European Research Council.Convocatoria: Advance Grant 2013. Nombre del proyecto: Selective Carbon-Carbon Bond Activation: A Wellspring of Untapped Reactivity, Código: ERC-AdG-338912. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO, Convocatoria: Proyectos I+D+i 2015. Nombre del proyecto: Carboxilación de materia orgánica con dióxido de carbono catalizada por metales de transición, Código: CTQ2015-65496-R. Ámbito del proyecto (Europeo, nacional o regional): Nacional, Agencia/entidad financiadora: MINECO. Convocatoria: Severo Ochoa Excellence Accreditation. Nombre del proyecto: Código: SEV-2013-0319
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acscentsci.8b00005
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.subjectAnionses
dc.subjectCatalystses
dc.subjectFunctionalizationes
dc.subjectHydrocarbonses
dc.subjectIsomerizationes
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Químicaes
dc.titleWalking metals for remote functionalizationes
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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This document is made available under the CC-BY 4.0 license http://creativecommons.org/licenses/by /4.0/ This document is the published version of a published work that appeared in final form in ACS Central Science. To access the final work, see DOI: https://doi.org/10.1021/acscentsci.8b00005
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