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Visible-light-promoted atom transfer radical cyclization of unactivated alkyl Iodides

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dc.contributor.authorShen, Yangyang
dc.contributor.authorCornella, Josep
dc.contributor.authorJuliá Hernández, Francisco
dc.contributor.authorMartin, Ruben
dc.contributor.departmentQuímica Inorgánica
dc.date.accessioned2025-01-07T10:15:12Z
dc.date.available2025-01-07T10:15:12Z
dc.date.issued2016-12-06
dc.description© 2016 American Chemical Society. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Accepted version of a Published Work that appeared in final form in ACS Catalysis. To access the final edited and published work see https://doi.org/10.1021/acscatal.6b03205
dc.description.abstractA visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative.
dc.formatapplication/pdfes
dc.format.extent6es
dc.identifier.citationACS Catal 2017, 7 (1), 409-412
dc.identifier.doihttps://doi.org/10.1021/acscatal.6b03205
dc.identifier.issnElectronic: 2155-5435
dc.identifier.urihttp://hdl.handle.net/10201/147918
dc.languageenges
dc.relation.ispartofÁmbito del proyecto (Europeo, nacional o regional): Europeo Agencia/entidad financiadora: European Research Council Convocatoria: Starting Grant 2011. Nombre del proyecto: Chasing a Fundamental Challenge in Catalysis: A Combined Cleavage of Carbon-Carbon Bonds and Carbon Dioxide for Preparing Functionalized Molecules Código: ERC-StG-277883. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Proyectos I+D+i 2015 Nombre del proyecto: CARBOXILACION DE MATERIA ORGANICA CON DIOXIDO DE CARBONO CATALIZADA POR METALES DE TRANSICION Código: CTQ2015-65496-R. Ámbito del proyecto (Europeo, nacional o regional): Nacional Agencia/entidad financiadora: MINECO Convocatoria: Severo Ochoa Excellence Accreditation. Nombre del proyecto: Código: SEV-2013-0319
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acscatal.6b03205
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectVisible light
dc.subjectAlkyl halide
dc.subjectPhotocatalysis
dc.subjectAtom economy
dc.subjectRadical cyclization
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Químicaes
dc.titleVisible-light-promoted atom transfer radical cyclization of unactivated alkyl Iodideses
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acscatal.6b03205
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