Publication: Visible-light-promoted atom transfer radical cyclization of unactivated alkyl Iodides
Authors
Shen, Yangyang ; Cornella, Josep ; Juliá Hernández, Francisco ; Martin, Ruben
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Publisher
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DOI
https://doi.org/10.1021/acscatal.6b03205
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info:eu-repo/semantics/article
Description
© 2016 American Chemical Society. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. This document is the Accepted version of a Published Work that appeared in final form in ACS Catalysis. To access the final edited and published work see https://doi.org/10.1021/acscatal.6b03205
Abstract
A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative.
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Citation
ACS Catal 2017, 7 (1), 409-412
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