Publication: Ionic liquids as an enabling tool to integrate reaction and separation processes
Authors
Alvarez, Elena ; Porcar, Raul ; Garcia-Verdugo, Eduardo ; V Luis, Santiago ; Lozano Rodríguez, Pedro ; Villa Aroca, Rocío
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Publisher
RSC
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DOI
https://doi.org/10.1039/C9GC02553G
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info:eu-repo/semantics/article
Description
Abstract
The development of advanced processes able to directly provide pure products by integrating
chemical transformations, product separation and recovery and reuse of the solvent and the
catalytic phases by straightforward and smart approaches, is a key feature to build green
chemical processes. The unique properties of ILs, one of the key enabling technologies, can
lead, when combined with (bio)catalysts, to amazing synergies not only improving the
catalytic efficiency (i.e. improved activity and enantioselectivity, enhanced stability, etc.), but
also allowing the design of smarts approaches for product separation (e.g. IL/scCO2 biphasic
reactors, membrane reactors, nanodrop systems, microfluidic devices, supported ionic liquid
phases, sponge-like ionic liquids, etc.), incorporating the full recovery and reuse of the catalyst
and the ILs phase. This tutorial review highlights representative examples of ILs-based
systems integrating reaction/separation as a tool for the development of sustainable chemical
processes leading to clean and pure chemical products.
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Citation
Green Chemistry , 2019, 21, 6527–6544
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