Publication:
Reacciones de adición oxidativa de halógenos a complejos carbonil pentafluorofenil bis-trifenil fosfína rodio (I) e iridio (I)

dc.contributor.authorTerreros, F.
dc.contributor.authorRoyo, P.
dc.date.accessioned2009-07-16T10:02:24Z
dc.date.available2009-07-16T10:02:24Z
dc.date.issued1971
dc.description.abstractIn a previous paper (1) we described the oxidatíve-addition reactíons of mercury (II) halides to the trans-MÍCcF.,) (CO) (PPh3)2, órgano complexes, M = Rh, Ir, highiighting the greater stabiHty of iridium (III) complexes, whose Ir—CeFj bond remains unaltered throughout the reaction. Since halogens are even more efficient addition reagents, it was of interest to study their reactions with the above mentioned complexes. The results which we observed are somewhat different from those recently described for the same type of reactions (2). The differences may be partly due to the structural changes induced by the different nature of the solvents and the different worth conditions used.en_EN
dc.formatapplication/pdfes
dc.format.extent8en_EN
dc.identifier.issn0463-9855
dc.identifier.urihttp://hdl.handle.net/10201/4881
dc.languagespaen_EN
dc.publisherMurcia : Universidad de Murcia, Sevicio de Publicacionesen_EN
dc.relation.ispartofAnales de la Universidad de Murcia. Cienciasen_EN
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.subjectReacciones químicasen_EN
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Químicaen_EN
dc.titleReacciones de adición oxidativa de halógenos a complejos carbonil pentafluorofenil bis-trifenil fosfína rodio (I) e iridio (I)en_EN
dc.typeinfo:eu-repo/semantics/articleen_EN
dspace.entity.typePublicationes
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