Publication: Reacciones de adición oxidativa de
halógenos a complejos carbonil
pentafluorofenil bis-trifenil fosfína rodio
(I) e iridio (I)
Authors
Terreros, F. ; Royo, P.
item.page.secondaryauthor
item.page.director
Publisher
Murcia : Universidad de Murcia, Sevicio de Publicaciones
publication.page.editor
publication.page.department
DOI
item.page.type
info:eu-repo/semantics/article
Description
Abstract
In a previous paper (1) we described the oxidatíve-addition reactíons
of mercury (II) halides to the trans-MÍCcF.,) (CO) (PPh3)2, órgano complexes,
M = Rh, Ir, highiighting the greater stabiHty of iridium (III) complexes,
whose Ir—CeFj bond remains unaltered throughout the reaction.
Since halogens are even more efficient addition reagents, it was of
interest to study their reactions with the above mentioned complexes.
The results which we observed are somewhat different from those
recently described for the same type of reactions (2). The differences may
be partly due to the structural changes induced by the different nature
of the solvents and the different worth conditions used.
publication.page.subject
Citation
item.page.embargo
Ir a Estadísticas
Sin licencia Creative Commons.