Publication:
Homo and heteroassembly of amide-based [2]rotaxanes using α,α′-dimethyl-p-xylylenediamines

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CC2019-JB_MS Tetramethyl HB-RTX.pdf(794.48 KB)
Date
2019-05-16
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Authors
Lopez-Leonardo, Carmen ; Martinez-Cuezva, Alberto ; Bautista, Delia ; Alajarín, Mateo ; Berná Cánovas, José
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Publisher
Royal Society of Chemistry
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Química Orgánica
DOI
10.1039/C9CC02701G
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info:eu-repo/semantics/article
Description
Abstract
The formation of [2] rotaxanes via a fumaramide-templated clipping reaction using alpha,alpha'-dimethyl-p-xylylenediamines is described. This process selectively affords two out of seven possible interlocked isomers due to a noticeable effect of the methyl groups on the in/ out disposition of the amide CO groups.
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Enlace de hidrógeno , Química Supramolecular , Estereoselectividad , Macrociclos , Moléculas Mecánicamente Enlazadas
Citation
Chem. Commun., 2019,55, 6787-6790.
URI
http://hdl.handle.net/10201/102261
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