Browsing by Subject "Macrociclos"

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    Homo and heteroassembly of amide-based [2]rotaxanes using α,α′-dimethyl-p-xylylenediamines
    (Royal Society of Chemistry, 2019-05-16) Lopez-Leonardo, Carmen; Martinez-Cuezva, Alberto; Bautista, Delia; Alajarín, Mateo; Berná Cánovas, José; Química Orgánica
    The formation of [2] rotaxanes via a fumaramide-templated clipping reaction using alpha,alpha'-dimethyl-p-xylylenediamines is described. This process selectively affords two out of seven possible interlocked isomers due to a noticeable effect of the methyl groups on the in/ out disposition of the amide CO groups.