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Saura Sanmartín, Adrián

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Saura Sanmartín, Adrián
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Universidad de Murcia. Departamento de Química Orgánica
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    Tailored cobalt framework with macrocyclic linkers for reversible dye adsorption
    (Springer Nature - Science China Press, 2026-06-18) Sánchez Andrada, Pilar; Peñaranda Navarro, Raquel; Martínez Gutiérrez, Diana; Pastor Vivero, Aurelia; Martínez Cuezva, Alberto; Saura Sanmartín, Adrián; Berná Cánovas, José; Saura Sanmartín, Adrián; Química Orgánica; Facultades de la UMU::Facultad de Química
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    Taming the elusive cyclo[n]carbon: how the mechanical bond stabilizes the unstable
    (Science China Chemistry (Springer Nature and Science China Press)., 2025-11-20) Raquel Peñaranda Navarro; Ana María Lax Carrillo; Saura Sanmartín, Adrián; Saura Sanmartín, Adrián; Química Orgánica; Facultades de la UMU::Facultad de Química
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    2-Isocyanoanilines and their mono-Boc-protected derivatives
    (Royal Society of Chemistry, 2025-07-15) Saura Sanmartín, Adrián; López Leonardo, Carmen; Alajarín Cerón, Mateo; Química Orgánica; Facultad de Química
    Among the variety of synthetically useful isocyanides, 2-isocyanoanilines have been scarcely reported in the chemical literature, despite the rich chemistry that expectedly could derive from the reactivities of their two functional groups. This is the case not only for the parent compound but also for most of their N-monosubstituted derivatives. The reason behind such behavior relies upon their chemical instability, apparently attributable to the presence of the N–H bond. Among these latter species, two tert-butyl carbamates are notorious exceptions, as they have been widely utilized in multicomponent reactions but poorly described. This review covers the chemistry of these compounds from a critical perspective, analyzing the causes of the instability of these privileged molecular scaffolds, as well as highlighting the reactivity of their mono-Boc-protected derivatives.
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