Browsing by Subject "Strain rings"

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    Nickel-catalyzed chemo-, regio- and diastereoselective bond formation through proximal C-C cleavage of benzocyclobutenones
    (Wiley, Gesellschaft Deutscher Chemiker, 2015-06-11) Juliá Hernández, Francisco; Ziadi, Asraa; Nishimura, Akira; Martin, Ruben; Química Inorgánica
    The first catalytic intermolecular proximal C1-C2 cleavage of Benzocyclobutenones (BCB) without prior carbonyl activation or employing noble metals has been developed. This protocol operates at room temperature and is characterized by an exquisite chemo-, regio- and diastereoselectivity profile, constituting a unique platform for preparing an array of elusive carbocyclic skeletons.