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Browsing by Subject "Michael Additions"

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    Stereoselectivity in Michael Addition Reactions Mediated by Interlocked and Non-Interlocked Organocatalysts
    (2020-03-03) Puigcerver, Julio; Martinez-Cuezva, Alberto; Alonso, Diego A.; Marin-Luna, Marta; Ros-Ñiguez, Diego; Tomas, Jose L.; Alajarín, Mateo; Berná Cánovas, José; Química Orgánica
    Mechanically interlockedmolecules have became ideal candidates for their application in numerous fields, highlighting their use as molecularmachines. Recently the employment of rotaxanes as switchable catalysts has experienced a great grown. Herein, we describe the application of a series of polyamide-based non-interlocked and interlocked systems organocatalysts for the enantiodivergent Michael addition of ketones to β-nitrostyrene.

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