Publication:
Stereoselectivity in Michael Addition Reactions Mediated by Interlocked and Non-Interlocked Organocatalysts

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Date
2020-03-03
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Authors
Puigcerver, Julio ; Martinez-Cuezva, Alberto ; Alonso, Diego A. ; Marin-Luna, Marta ; Ros-Ñiguez, Diego ; Tomas, Jose L. ; Alajarín, Mateo ; Berná Cánovas, José
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Química Orgánica
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info:eu-repo/semantics/conferenceObject
Description
Abstract
Mechanically interlockedmolecules have became ideal candidates for their application in numerous fields, highlighting their use as molecularmachines. Recently the employment of rotaxanes as switchable catalysts has experienced a great grown. Herein, we describe the application of a series of polyamide-based non-interlocked and interlocked systems organocatalysts for the enantiodivergent Michael addition of ketones to β-nitrostyrene.
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Michael Additions , Asymetric synthesis , Organocatalysis , Rotaxanes , Organocatalysis
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http://hdl.handle.net/10201/102882
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