Publication:
Applications of halogen-atom transfer (XAT) for the generation of carbon radicals in synthetic photochemistry and photocatalysis

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2._Manuscript_final.pdf(8.1 MB)
Date
2022-01-26
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Authors
Juliá Hernández, Fabio ; Constantin, Timothee ; Leonori, Daniele
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Publisher
American Chemical Society
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Química Inorgánica
DOI
https://doi.org/10.1021/acs.chemrev.1c00558
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Description
© 2021 American Chemical Society. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted Manuscript version of a Published Work that appeared in final form in Chemical Reviews. To access the final edited and published work see https://doi.org/10.1021/acs.chemrev.1c00558
Abstract
The halogen-atom transfer (XAT) is one of the most important and applied processes for the generation of carbon radicals in synthetic chemistry. In this review, we summarize and highlight the most important aspects associated with XAT and the impact it has had on photochemistry and photocatalysis. The organization of the material starts with the analysis of the most important mechanistic aspects and then follows a subdivision based on the nature of the reagents used in the halogen abstraction. This review aims to provide a general overview of the fundamental concepts and main agents involved in XAT processes with the objective of offering a tool to understand and facilitate the development of new synthetic radical strategies.
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Citation
Chemical Reviews, 2022, Vol. 122, Issue 2, pp. 2292–2352
URI
http://hdl.handle.net/10201/149194
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