Preparation of organogold(III) complexes by oxidizing dichlordethanedigold(I), or bis(pentafluorophenyl)-mu-bis(diphenylphosphino)ethanedigold(I)

Publication:
Preparation of organogold(III) complexes by oxidizing dichlordethanedigold(I), or bis(pentafluorophenyl)-mu-bis(diphenylphosphino)ethanedigold(I)

dc.contributor.author	Uson, R.
dc.contributor.author	Laguna, A.
dc.contributor.author	Vicente, J.
dc.contributor.author	Garcia, J.
dc.contributor.department	Química Inorgánica
dc.contributor.department	Química Inorgánica de la Universidad de Zaragoza
dc.date.accessioned	2019-10-29T16:13:17Z
dc.date.available	2019-10-29T16:13:17Z
dc.date.created	1975
dc.date.issued	2019-10-29
dc.description.abstract	The oxidation of compounds of the type XAu(dpe)AuX [dpe = l,Z-bis(diphenylphosphino) ethane] leads to organogold(II1) complexes. When X is Cl, treatment with BrTl(C,F,), leads to oxidative addition of two C6 FS groups to each gold atom and formation of CI(C,F,)2 Au(dpe)Au(& F5)* Cl, which by metathesis with KBr or KI gives the corresponding bromo (or iodo) derivative. When X is C6 FS oxidation with halogens leads in the case of X’ = Cl or Br to formation of Xi (C, FS )Au(dpe)Au(& F5 )X; whereas, for X’ = I reductive elimination of I&F5 takes place to give IAu(dpe)AuI.	es
dc.format	application/pdf	es
dc.format.extent	6	es
dc.identifier.doi	http://dx.doi.org/10.1016/S0022-328X(00)91386-X
dc.identifier.uri	http://hdl.handle.net/10201/76102
dc.language	eng	es
dc.rights	info:eu-repo/semantics/openAccess	es
dc.subject	Aril organomet Au(3) Au(1) oxidacion C6F5 dpe	es
dc.title	Preparation of organogold(III) complexes by oxidizing dichlordethanedigold(I), or bis(pentafluorophenyl)-mu-bis(diphenylphosphino)ethanedigold(I)
dc.type	info:eu-repo/semantics/article	es
dspace.entity.type	Publication	es