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Sustainable chemo-enzymatic synthesis of glycerol carbonate (meth)acrylate from glycidol and carbon dioxide enabled by ionic liquid technologies

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dc.contributor.authorVilla Aroca, Rocío
dc.contributor.authorPorcar, Raul
dc.contributor.authorNieto Cerón, Susana
dc.contributor.authorDonaire González, Antonio
dc.contributor.authorGarcía-Verdugo, Eduardo
dc.contributor.authorLuis, Santiago V.
dc.contributor.authorLozano Rodríguez, Pedro
dc.contributor.departmentBioquímica y Biología Molecular B e Inmunología
dc.contributor.otherFacultad de Química
dc.date.accessioned2025-01-09T17:25:59Z
dc.date.available2025-01-09T17:25:59Z
dc.date.copyright© 2021, The Royal Society of Chemistry
dc.date.issued2021-05-06
dc.description.abstractA sustainable chemo-enzymatic process for producing both glycerol carbonate acrylate (GCA) and glycerol carbonate methacrylate (GCMA), as useful monomers for the preparation of biodegradable plastic materials, has been carried out by taking advantage of ionic liquid (IL) technologies. The process consiste of two consecutive catalytic steps, which can be carried out by either sequential or one-pot experimental approaches. Glycidyl (meth)acrylate was firstly synthesized by enzymatic transesterification of (meth)acrylate vinyl ester with glycidol in Sponge Like Ionic Liquids (SLILs) as the reaction medium (100% yield after 6 h at 60 °C). SLILs not only provided a suitable reaction medium, but also allowed the simple isolation of the resulting glycidyl esters as an IL-free pure fraction through a straightforward cooling/centrifugation protocol. The second step consisted of the synthesis of GCA, or GCMA, as the outcome of the cycloaddition of CO2 to the obtained glycidyl acrylate or glycidyl methacrylate, respectively, catalysed by a covalently attached 1-decyl-2-methylimidazolium moiety (Supported Ionic Liquid-Like Phase, SILLP) in a solvent-free system and under mild conditions (60 °C, 1–10 bar), leading to up to 100% yield after 6 h. The components of the reaction system (biocatalyst/SLIL/SILLP) can be fully recovered and reused for atleast 6 cycles with unchanged catalytic performance.es
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dc.format.extent10es
dc.identifier.citationGreen Chemistry, 2021, Vol. 23, Issue 11, pp. 4191-4200
dc.identifier.doihttps://doi.org/10.1039/D1GC01096D
dc.identifier.eissn1463-9270
dc.identifier.issn1463-9262
dc.identifier.urihttp://hdl.handle.net/10201/148165
dc.languageenges
dc.publisherRoyal Society of Chemistry
dc.relationThis work was partially supported by RTI2018-098233-B-C21 and RTI2018-098233-B-C22 (Ministerio de Ciencia, Innovación y Universidades), 20790/PI/18 (Fundacion SENECA CARM), and UJI-B2019-40 (Pla de Promoció de la Investigació de la Universitat Jaume I) grants.es
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2021/gc/d1gc01096d
dc.rightsinfo:eu-repo/semantics/restrictedAccesses
dc.titleSustainable chemo-enzymatic synthesis of glycerol carbonate (meth)acrylate from glycidol and carbon dioxide enabled by ionic liquid technologieses
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/publishedVersión
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