Publication:
Exploring the structure andelectronic properties of individual hybrid GO/rGOflakes

dc.contributor.authorNavarro-Rodriguez, Mario
dc.contributor.authorCamus, Victor
dc.contributor.authorCros, Ana
dc.contributor.authorGarro, Nuria
dc.contributor.authorSomoza, Andres M.
dc.contributor.authorPalacios-Lidon, Elisa
dc.contributor.departmentFísica
dc.date.accessioned2025-01-20T18:12:33Z
dc.date.available2025-01-20T18:12:33Z
dc.description©2024. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Published version of a Published Work that appeared in final form in Applied Surface Science. To access the final edited and published work see https://doi.org/10.1016/j.apsusc.2023.158611
dc.description.abstractDespite its great potential, the use of graphene oxide (GO) in sensors, photocatalysis, or biomedicine applications is limited by its low conductivity. This drawback is typically overcome by using its reduced form (rGO) albeit sacrificing some of its extensive chemical properties. In this study, we unveil a nonuniform reduction process that enables the fabrication of hybrid flakes consisting of both size tunable GO and rGO regions. The nanoscale resolution of Kelvin probe force microscopy together with co-localized Raman spectroscopy allow us to correlate the local reduction degree with the nanoscale electronic properties, chemical composition, and structural defects. Additionally, we introduce a reliable metric for quantifying the extent of reduction. This research opens up possibilities for the development of new 2D nanohybrid materials that combine the high reactivity of GO and the enhanced conductivity of rGO, enabling applications in selective functionalization.es
dc.formatapplication/pdfes
dc.format.extent8es
dc.identifier.citationApplied Surface Science 642 (2024) 158611
dc.identifier.doihttps://doi.org/10.1016/j.apsusc.2023.158611
dc.identifier.issnPrint: 2469-9950
dc.identifier.issnElectronic: 2469-9969
dc.identifier.urihttp://hdl.handle.net/10201/148846
dc.languageenges
dc.relationThe authors thank the funding agencies MCIN/AEI/ 10.13039/501100011033 through projects PID2019-104272RB-C52 and PID2019-104272RB-C53; “ERDF A way of making Europe”; and Generalitat Valenciana through project CIPROM-2021-75; and the Advanced Materials programme by MCIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat Valenciana (Grant MFA/2022/007). M.N work was financed by the grant PID2019-104272RB-C52/PRE2020-094503 funded by MCIN/AEI/ 10.13039/501100011033 and by “ESF Investing in your future ”.es
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0169433223022912es
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectGraphene oxidees
dc.subjectReduced graphene oxide
dc.subjectKelvin probe force microscopy
dc.subjectRaman spectroscopy
dc.subjectNanoscale conductivity
dc.subject.otherCDU::6 - Ciencias aplicadases
dc.titleExploring the structure andelectronic properties of individual hybrid GO/rGOflakeses
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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