The Coordination and Supramolecular Chemistry of Gold Metalloligands

Gil-Rubio, Juan; Vicente, José

Publication:
The Coordination and Supramolecular Chemistry of Gold Metalloligands

dc.contributor.author	Gil-Rubio, Juan
dc.contributor.author	Vicente, José
dc.contributor.department	Química Inorgánica
dc.date.accessioned	2020-03-17T10:57:12Z
dc.date.available	2020-03-17T10:57:12Z
dc.date.created	2017
dc.date.issued	2017-10-13
dc.description.abstract	This review article deals with the use of gold metalloligands as building blocks for the assembly of heterometallic complexes. Several families of gold complexes decorated with crown-ether, amide, pyridine, bipyridine, terpyridine, carboxylato, aminoacid or π-alkyne binding sites have been reported. Adducts of these metalloligands with alkaline or transition metal cations, or with transition metal or lanthanide complexes, have been isolated and structurally characterized. The reported heterometallic species range from simple dinuclear complexes to self-assembled supramolecules, coordination polymers or solids. New structural motifs have been found in these complexes. Most of these metalloligands and complexes are photoluminescent and some of them show switchable emissions based on the formation and rupture of metallophilic contacts. Potential applications as sensors, sensitizers, in vivo imaging agents and anticancer drugs are envisaged.	es
dc.description.sponsorship	Ministerio de Economía y Competitividad (grant CTQ2015-69568-P, with FEDER support). Fundación Séneca (grant 19890/GERM/15)	es
dc.format	application/pdf	es
dc.format.extent	17	es
dc.identifier.citation	Chem. Eur. J. 24(1), 32-46 (2018)
dc.identifier.doi	10.1002/chem.201703574
dc.identifier.issn	1521-3765
dc.identifier.uri	http://hdl.handle.net/10201/88162
dc.language	eng	es
dc.publisher	Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim	es
dc.relation.publisherversion	https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201703574	es
dc.rights	info:eu-repo/semantics/openAccess	es
dc.subject	Gold	es
dc.subject	Self-Assembly	es
dc.subject	Coordination Complexes	es
dc.subject.other	CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica	es
dc.title	The Coordination and Supramolecular Chemistry of Gold Metalloligands	es
dc.type	info:eu-repo/semantics/article	es
dspace.entity.type	Publication	es