Publication:
Light-driven exchange between extended and contracted lasso-like isomers of a bistable [1]rotaxane

Simple item page
dc.contributor.authorSaura-Sanmartin, Adrian
dc.contributor.authorMartinez-Cuezva, Alberto
dc.contributor.authorPastor Vivero, Aurelia
dc.contributor.authorBautista, Delia
dc.contributor.authorBerná Cánovas, José
dc.contributor.departmentQuímica Orgánica
dc.date.accessioned2021-01-27T12:21:34Z
dc.date.available2021-01-27T12:21:34Z
dc.date.created2018
dc.date.issued2018-09-13
dc.description.abstractThe synthesis of a set of benzylic amide [1]rotaxanes via a self-templating clipping approach is described. This methodology supposes the 1+1 coupling of isophthaloyl dichloride with an acyclic diamine precursor incorporating a templating arm. The structure of the threaded compounds was determined in both solution and solid state. The conversion into the corresponding unthreaded isomers, also obtained by deslipping of [2]rotaxane models, was evaluated in competitive and non-competitive hydrogen-bonding solvents. The switch of the extended and contracted lasso-like isomers of a bistable [1]rotaxane by an olefin isomerization promoted by UV light irradiation was also accomplished and their ring positional integrity examined.es
dc.formatapplication/pdfes
dc.format.extent7es
dc.identifier.citationOrganic & Biomolecular Chemistry 2018, 16 (38) , 6980-6987.
dc.identifier.doi10.1039/C8OB02234H
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/10201/101817
dc.languageenges
dc.publisherRoyal Society of Chemistryes
dc.relationMinisterio de Economía, Industria y Competitividad. Programa Estatal de Fomento de la Investigación Científica y Técnica de Excelencia. Proyectos I+D 2017 (Nacional). Nombre del proyecto: Reactividad y Conmutación de Moléculas Mecanizadas. Código: CTQ2017-87231-P. Fundación Séneca (Comunidad Autónoma de la Región de Murcia). Ayudas para la realización de proyectos de investigación destinadas a grupos competitivos (Programa Séneca 2014) (Regional). Nombre del proyecto: Cicloadiciones de Ceteniminas Catalizadas por Metales de Transición y Reacciones de Ceteniminas con Carbenos Nucleofílicos y Bencino. Conmutación y Organización Tridimensional de Moléculas Entrelazadas. Código: 19240/PI/14.es
dc.relation.isreplacedbyhttps://doi.org/10.1039/C8OB02234Hes
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2018/OB/C8OB02234Hes
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rightsAtribución-NoComercial-SinDerivadas 3.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.subjectMoléculas Mecánicamente Enlazadases
dc.subjectMáquinas Moleculareses
dc.subjectAuto-inclusiónes
dc.subjectTopología Químicaes
dc.subjectConmutador Fotoquímicoes
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánicaes
dc.titleLight-driven exchange between extended and contracted lasso-like isomers of a bistable [1]rotaxanees
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Self-Archived MS-JBerna_Photoactive Amide-base 1Rtx.pdf
Size:
875.61 KB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
1.39 KB
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Artículos