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Maximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactions

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dc.contributor.authorSaura-Sanmartin, Adrian
dc.contributor.authorPastor Vivero, Aurelia
dc.contributor.authorMartinez-Cuezva, Alberto
dc.contributor.authorBerná Cánovas, José
dc.contributor.departmentQuímica Orgánica
dc.date.accessioned2023-04-24T11:05:44Z
dc.date.available2023-04-24T11:05:44Z
dc.date.created2021
dc.date.issued2021-11-30
dc.description©2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in [Chemical Communications]. To access the final edited and published work see[https://doi.org/10.1039/D1CC05942D]es
dc.description.abstractSelf-templating two-component coupling reactions allowed the isolation of two threaded products with different molecular sizes: a lasso-type [1]rotaxane and a [c2]daisy chain rotaxane. Their distribution in the final reaction mixture varies as a factor of the concentration of the reactants. Through this methodology we obtained a large 84-membered cyclic multistation [2]rotaxane.es
dc.formatapplication/pdfes
dc.format.extent4es
dc.identifier.citationChem. Commun., 2022, 58, 290-293.
dc.identifier.doihttps://doi.org/10.1039/D1CC05942D
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.urihttp://hdl.handle.net/10201/130296
dc.languageenges
dc.publisherRoyal Society of Chemistryes
dc.relationThis research was supported by the Ministerio de Ciencia e Innovacion of Spain (PID2020-113686GB-I00 /MICIN/AEI/10.13039/501100011033 and Fundacion Seneca-CARM (20811/PI/18). Adrian Saura-Sanmartin also thanks Fundacion Seneca-CARM for his contract (20259/FPI/17).es
dc.relation.isreplacedbyhttps://pubs.rsc.org/en/content/articlelanding/2022/CC/D1CC05942Des
dc.relation.publisherversionhttps://pubs.rsc.org/en/content/articlelanding/2022/CC/D1CC05942Des
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectMechanical bondes
dc.subject[c2]DAISY CHAIN ROTAXANEes
dc.subjectLasso compoundses
dc.subjectClipping reactionses
dc.subjectNMR Diffusion experimentses
dc.subjectSupramolecular chemistryes
dc.subject.otherCDU::5 - Ciencias puras y naturales::54 - Química::547 - Química orgánicaes
dc.titleMaximizing the [c2]daisy chain to lasso ratio through competitive self-templating clipping reactionses
dc.typeinfo:eu-repo/semantics/articlees
dspace.entity.typePublicationes
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