Publication: Synthesis of spiro-oxoindoles through Pd-catalyzed remote C–H alkylation using alpha-diazocarbonyl compounds
Authors
Pérez-Gómez, Marta ; Hernández-Ponte, Sergio ; Bautista, Delia ; García-López, José-Antonio
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Publisher
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DOI
10.1039/c7cc00065k
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info:eu-repo/semantics/article
Description
Abstract
In this communication we describe a new route to spiro-oxoindoles derivatives through a novel Pd-catalyzed cascade process. This reaction is based on the remote C–H activation performed by sigma-alkyl Pd(II) species generated in situ via intramolecular carbopalladation of alkenes, followed by insertion of a carbenoid coupling partner.
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Citation
Chem.Commun.,2017,53, 2842-2845
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