Dihaloperhaloaryl triphenylarsine gold(III) complexes

Publication:
Dihaloperhaloaryl triphenylarsine gold(III) complexes

dc.contributor.author	Usón, Rafael
dc.contributor.author	Laguna, Antonio
dc.contributor.author	Vicente, José
dc.contributor.department	Química Inorgánica
dc.contributor.department	Química Inorgánica de la Universidad de Zaragoza
dc.date.accessioned	2009
dc.date.available	2009-03-13T19:24:14Z
dc.date.created	1975
dc.description.abstract	When C6CISAuAsPh3 reacts with halogens, oxidation of the gold(I) complex and formation of X2Au(C6C15)AsPh3 (X = Cl, Br, I) take place. However, when C6F5AuAsPh3 reacts with halogens, oxidation is only observed in the case of Cl2 whilst I2 (totally) and Br2 (partially) split the Au-C bond. This behaviour is contrary to that observed with C6F5AuPPh3 and halogens, where the tendency to split the Au-C bond decreases in the sequence C! > Br > I.	en_EN
dc.format	application/pdf	es
dc.format.extent	8	en_EN
dc.identifier.uri	http://hdl.handle.net/10201/3614
dc.language	eng	en_EN
dc.relation.ispartof	J. Organomet. Chem. 86 (1975) 415	en_EN
dc.rights	info:eu-repo/semantics/openAccess	es
dc.subject	Aril Aryl organometalico organometallics Au(III) Au(I) gold	en_EN
dc.subject	Oro	en_EN
dc.subject	Arsina	en_EN
dc.subject	Arsine	en_EN
dc.subject	AsPh3	en_EN
dc.subject	C6F5	en_EN
dc.subject	C6Cl5	en_EN
dc.subject	Oxidation	en_EN
dc.subject	Oxidación	es
dc.subject.other	CDU::5 - Ciencias puras y naturales	en_EN
dc.title	Dihaloperhaloaryl triphenylarsine gold(III) complexes	en_EN
dc.type	info:eu-repo/semantics/article	en_EN
dspace.entity.type	Publication	es