Publication:
Access to ligand-stabilized PH-containing phosphenium complexes

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dc.contributor.authorBiskup, David
dc.contributor.authorSchnakenburg, Gregor
dc.contributor.authorEspinosa Ferao, Arturo Francisco
dc.contributor.authorStreubel, Rainer
dc.contributor.departmentQuímica Orgánica
dc.date.accessioned2024-05-28T22:11:02Z
dc.date.available2024-05-28T22:11:02Z
dc.date.issued2024-01-04
dc.description©2024. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ This document is the Accepted, version of a Published Work that appeared in final form in Dalton Transactions. To access the final edited and published work see https://doi.org/10.1039/d3dt03869f
dc.description.abstractWhile the chemistry of phosphenium compounds, including metal complexes thereof, is very well established, few derivatives having a P–H bond have been described, yet. This work describes rational access to donor-stabilised phosphenium metal complexes possessing a P–H bond using protonation reactions of stable phosphinidene complex adducts. While most Brønsted–Lowry acids yield formal 1,1-addition products at the phosphorus centre under the loss of the donor, super-strong acids having weakly coordinating anions enable access to donor-stabilised P–H hosphenium complex salts. The latter possess N-methylimidazole as a donor (to phosphorus) and the N–P interaction has been studied theoretically.
dc.formatapplication/pdfes_ES
dc.format.extent9
dc.identifier.citationDalton Transactions 2024, 53, 2517–2525
dc.identifier.doihttps://doi.org/10.1039/d3dt03869f
dc.identifier.issnPrint: 1477-9226
dc.identifier.issnElectronic: 1477-9234
dc.identifier.urihttp://hdl.handle.net/10201/141926
dc.languageenges_ES
dc.publisherRoyal Society of Chemistry
dc.relationFinancial support from the Deutsche Forschungsgemeinschaft (STR 411/45-1) and the University of Bonn
dc.rightsinfo:eu-repo/semantics/openAccess*
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectDFT calculationses_ES
dc.subjectPhosphenium complexeses_ES
dc.titleAccess to ligand-stabilized PH-containing phosphenium complexeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dspace.entity.typePublicationes
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