Publication: Synthesis and Solution Behavior of some Bis[ Z-{(dimethylamino)methyl~phenyl]gold(III) Complexes
Authors
Vicente, J. ; Bermúdez, M. D. ; Sánchez-Santano, M. J. ; Payá, J.
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info:eu-repo/semantics/article
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Abstract
[Au(2-C6H4CH,NMe,)ClZ] reacts with [Hg(2-
C6H4CH2NMe,), ] (2/l) or with [Hg(2-C6H4CH2-
NMe,)Cl] (l/l) both in the presence of an excess of
[Me,N]Cl to give [Au(2-Ce,H4CH#Me&C1) (1)
which reacts with KCN or AgC104 to give [Au(2-
C6H4CH2NMe2),CN] (2) or [Au(2-C6H4CH2-
NME,), ]C104 (3), respectively. The solution behavior
of these complexes is studied by NMR spectroscopy.
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