Non-arylic DiorganothalIium Derivatives obtained by Metallation. Synthesis and Isolation of the First DiketonyIthalIium (III) Complexes

Vicente, J.; Abad, J. A.; Cara, G.; Gutierrez-Jugo, J. F.

Publication:
Non-arylic DiorganothalIium Derivatives obtained by Metallation. Synthesis and Isolation of the First DiketonyIthalIium (III) Complexes

dc.contributor.author	Vicente, J.
dc.contributor.author	Abad, J. A.
dc.contributor.author	Cara, G.
dc.contributor.author	Gutierrez-Jugo, J. F.
dc.contributor.department	Química Inorgánica
dc.date.accessioned	2019-11-25T12:06:37Z
dc.date.available	2019-11-25T12:06:37Z
dc.date.created	1992
dc.date.issued	2019-11-25
dc.description.abstract	Addition of trifluoroacetic or trifluoromethanesulfonic acid to solutions of thaIlium(l1l) trifluoroacetate in acetone results in formation of the compounds [TI{CH,C(O)Me},X] (X = CF,CO, l a or CF,SO, 1 b. Compound 1 b reacts in a 1 : 1 ratio with LiCl or KBr giving the halogeno derivatives [TI{CH,C(O)Me},Y] (Y = CI 2a or Br 2b). Compound 2a reacts with [N(PPh,),]CI yielding the anionic complex “(PPh,),] [TI{CH,C(O)Me},CI,] 3. The reaction of 1 b with 2,2‘-bipyridine (bipy) gives [{TI[CH,- C(O)Me],(p-CF,SO,) (bipy)},] 4 in which each thallium atom has a distorted six-co-ordination with the acetonyl ligands in trans positions and two cis positions occupied by two bridging triflate anions.	es
dc.format	application/pdf	es
dc.format.extent	3	es
dc.identifier.uri	http://hdl.handle.net/10201/76924
dc.language	eng	es
dc.rights	info:eu-repo/semantics/openAccess	es
dc.rights	Attribution-NonCommercial-NoDerivatives 4.0 International	*
dc.rights.uri	http://creativecommons.org/licenses/by-nc-nd/4.0/	*
dc.subject	organometallic Tl metallation ketonyl RX
dc.subject.other	CDU::5 - Ciencias puras y naturales::54 - Química::546 - Química inorgánica
dc.title	Non-arylic DiorganothalIium Derivatives obtained by Metallation. Synthesis and Isolation of the First DiketonyIthalIium (III) Complexes
dc.type	info:eu-repo/semantics/article	es
dspace.entity.type	Publication	es