Publication: Synthesis of the First Example of a Cyclometallated ortho-Nitrophenyl Complex. X-Ray Molecular Structure of Carbonyl(chloro)bis(o-nitrophenyl-C,O)rhodium
Authors
Vicente, J. ; Martín, J. ; Chicote Olalla, María Teresa ; Solans, X. ; Miravitlles, C.
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info:eu-repo/semantics/article
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Abstract
The complex [RhCI(C0)2]2 reacts at room temperature with [Hg(2-C6H4N02)2] (1 : 2) to give metallic mercury and the complex [Rh(2-C6H4N(0)o)2CI(CO)w] hose crystal structure shows an octahedral co-ordination with one oxygen atom of each nitrophenyl ligand co-ordinated to the rhodium atom.
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