Browsing by Subject "Self-assembly"

Now showing 1 - 2 of 2
  • Thumbnail Image
    Publication
    Open Access
    FAIR data for compunds included in the article "Control of the assembly of a cyclic hetero[4]pseudorotaxane from a self-complementary [2]rotaxane"
    (2023-03-22) Saura-Sanmartin, Adrian; Nicolas-Garcia, Tomas; Pastor, Aurelia; Quiñonero, David; Alajarin, Mateo; Martinez-Cuezva, Alberto; Berna, Jose; Química Orgánica
  • Thumbnail Image
    Publication
    Open Access
    Hydrogen-bonded azaphenacene: a strategy for the organization of π-conjugated materials
    (2018-03-02) Gómez, Paula; Georgakopoulos, Stamatis; Cerón, José Pedro; da Silva, Iván; Más-Montoya, Miriam; Pérez, José; Tárraga Tomás, Alberto; Curiel Casado, David; Química Orgánica
    A centrosymmetric fused polyheteroaromatic system, namely 7-azaindolo[2,3-h]α-carboline has been synthesized. The pentacyclic structure includes rationally located hydrogen bond donor and hydrogen bond acceptor sites to induce its self-assembly. The molecular units associate forming an extended monodimensional arrangement that further self-organizes through π-stacking. The optical, electrochemical, X-ray diffraction, computational and electronic characterization in organic field effect transistors proves the utility of hydrogen bond-directed self-assembly as strategy to enhance edge-to-edge interactions and orbital overlap that contribute to the charge transport properties in π-conjugated systems.