Browsing by Subject "Biodiesel"

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    Approach to biodiesel production from microalgae under supercritical conditions by the PRISMA method
    (Elsevier, 2019) Ortiz Martínez, Víctor Manuel; Andreo Martínez, Pedro; García Martínez, Nuria; Pérez de los Ríos, Antonia; Hernández Fernández, Francisco José; Quesada Medina, Joaquín; Química Agrícola, Geología y Edafología
    Increasing energy demands lead to the search for sustainable biofuels such as biodiesel from renewable sources such as algal biomass. Specially, microalgae have become increasingly popular as biodiesel feedstock due to their fast-growing rates and relatively high level of lipids. The non-catalytic transesterification reaction of microalgae oil under supercritical conditions in the presence of alcohols is an efficient process for biodiesel production and can overcome some of the limitations posed by subcritical catalytic transesterification. Two-step and one-step processes have been reported for this purpose, in the last case with extraction and transesterification stages being performed simultaneously. This works offer a systematic review using the PRISMA methodology analyzing the status of this research topic and identifying future research strategies. With this work, PRISMA methodology is applied for the first time within technological engineering fields. Moreover, this is the first specific overview on the production of biodiesel from microalgae under supercritical conditions. Several key factors such as microalgae type and operation variables including extraction oil, temperature and reaction time, pressure, water content in biomass, alcohol excess and final biodiesel properties are discussed. Further efforts need to be done in order to study the continuous biodiesel production by the development of integrated processes that involve both microalgae cultivation and biodiesel production.
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    Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis
    (Elsevier, 2020) Andreo Martínez, Pedro; Ortiz Martínez, Víctor Manuel; García Martínez, Nuria; Pérez de los Ríos, Antonia; Hernández Fernández, Francisco José; Quesada Medina, Joaquín; Química Agrícola, Geología y Edafología
    The demand for biodiesel as an alternative and potentially renewable fuel is constantly rising. Biodiesel production from lipids in supercritical conditions offers several advantages over other catalytic processes. These advantages include high-efficiency production, environmental friendliness and the possibility of using a broad range of feedstock sources. As a consequence, there is a great interest in biodiesel production research using supercritical fluids as a sustainable technology option. In this sense, bibliometric reviews can be very useful for the interpretation of scientific production and research trends in this field. Thus, this work presents a scientometric study on biodiesel production research under supercritical conditions from 2001 to 2019, based on the Web of Science© database. 608 articles were analyzed and the parameters considered were: (i) publication type, language and output characteristics, (ii) Lotka's Law, Price's index and h-index, (iii) authors, countries and institutions collaboration analysis, (iv) publication performance by authors, journals, institutions and countries and (v) author keywords, single title words and keywords Plus analysis. The productivity patterns of authors, journals, institutions and authors keywords were found to fit Lotka's law. In terms of feedstock used in supercritical conditions, the bibliometric analysis showed a clear transition from first- to third-generation biodiesel, with special attention paid to the experimental study of supercritical reaction conditions. By contrast, further process optimization, the reduction of the severity of the supercritical conditions through devised strategies to lower energy consumption and further economic analysis are still needed, among other factors, for the real implementation of the technology.